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Kinetic isotope effect / Physical organic chemistry / Catalysis / Redox / Chemistry / Chemical kinetics / Chemical reactions


Article pubs.acs.org/IC Oxygen Kinetic Isotope Effects upon Catalytic Water Oxidation by a Monomeric Ruthenium Complex Alfredo M. Angeles-Boza and Justine P. Roth*
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Document Date: 2012-09-13 16:49:22


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File Size: 1,15 MB

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City

Rapaport / Lancaster / Lewis / MeOD-d3 / Baltimore / New York / Eisenstadt / London / Norcross / /

Company

Cambridge Isotope Laboratories / Millipore / Fisher Scientific / Sigma-Aldrich / Agilent / Merbach A. E. / Yellow Springs Inc. / Hupp / Environmental Isotope Laboratory / BASF / ASSOCIATED CONTENT / /

Country

United States / /

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Event

FDA Phase / Music Album Release / /

Facility

Plant Biol / University of Waterloo / Environmental Isotope Laboratory / Johns Hopkins University / /

IndustryTerm

free-energy reaction coordinate diagram / helium gas / chemical oxidation / activation free-energy barriers / ceric sulfate solution / transition-state energy / law plot / reduced metal catalyst / aqueous solution / energy differences / acidic solution / neutral solution / lower estimated free-energy barriers / helium-saturated acidic solution / Chemical shifts / free-energy surface / helium carrier gas / labeled metal complex / neutral aqueous solutions / acidic and neutral media / chemicals / /

MusicAlbum

O2 / /

Organization

Justine P. Roth* Department of Chemistry / Johns Hopkins University / University of Waterloo / Department of Earth and Planetary Sciences / Department of Earth / /

Person

Justine P. Roth / Wasylenko / Alfredo M. Angeles-Boza / Ben Passey / Zahid Ertim / Eric Sun / Wang Voorhis / Van Voorhis / Nocera / Chris Cramer / /

Position

kBT/h exp−ΔG /RT / D. J. / AUTHOR INFORMATION Corresponding Author *E-mail / /

Product

3Cl2 / H2O / /

ProgrammingLanguage

E / /

ProvinceOrState

Maryland / Nova Scotia / /

Technology

thermodynamics / HPO / CO2 exchange protocol / http / /

URL

pubs.acs.org / /

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